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Named Organic Reactions
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Wolf Rearrangement
Define : When an α-diazo ketone is decomposed thermally photo-chemically or catalytically and converted to ketone by removal of dinitrogen, it is called wolf rearrangement. The reaction was given by Ludwing Wolf in 1902. Reaction: When ketene is formed it acts as an intermediate for forming acid Ester and Amide. Mechanism of Wolf Rearrangement: Wolf…